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Creators/Authors contains: "Walker, Morgan"

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  1. ; ; ; ; ; ; ; ; ; ; et al (, Nature Physics)
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  2. ; ; ; ; ; ; ; ; ; ; et al (, Nature Communications)
    Abstract The shape of 3d-orbitals often governs the electronic and magnetic properties of correlated transition metal oxides. In the superconducting cuprates, the planar confinement of the$${d}_{{x}^{2}-{y}^{2}}$$ d x 2 − y 2 orbital dictates the two-dimensional nature of the unconventional superconductivity and a competing charge order. Achieving orbital-specific control of the electronic structure to allow coupling pathways across adjacent planes would enable direct assessment of the role of dimensionality in the intertwined orders. Using CuL3and PrM5resonant x-ray scattering and first-principles calculations, we report a highly correlated three-dimensional charge order in Pr-substituted YBa2Cu3O7, where the Prf-electrons create a direct orbital bridge between CuO2planes. With this we demonstrate that interplanar orbital engineering can be used to surgically control electronic phases in correlated oxides and other layered materials. 
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  3. ; ; ; ; ; ; ; ; (, Journal of the American Chemical Society)
    null (Ed.)
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  4. ; ; ; ; ; (, Journal of the American Chemical Society)
    null (Ed.)
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  5. ; ; ; ; (, The Journal of Organic Chemistry)
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